Chirality Recognition by a Clay Surface Modified with Metal Complexes.
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چکیده
منابع مشابه
Molecular recognition of star-burst tetranuclear Ru(III) complexes on a chirally modified clay surface.
Star-burst tetranuclear Ru(iii) complexes, Delta-(or Lambda-)[{Delta-(or Lambda-)-Ru(iii)(acac)(2)(taet)}(3)Ru(iii)] (acac = acetylacetonato; taet = tetraacetylethanato), were prepared and resolved into eight enantiomers on a column packed with an ion-exchange adduct of a clay and Delta-[Ru(ii)(phen)(3)](2+) (phen = 1,10-phenanthroline), demonstrating that the dual chiralities of the central an...
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ژورنال
عنوان ژورنال: NIPPON KAGAKU KAISHI
سال: 1994
ISSN: 2185-0925,0369-4577
DOI: 10.1246/nikkashi.1994.853